Bio-based wash primer expands validation on industrial carbon steels

The growing need to replace chromated primers used in steel corrosion protection has driven the development of safer and more sustainable alternatives. BIO FLAV PRIMER, a bio-based wash primer developed from valorized agro-industrial byproducts offers an alternative to conventional primers formulated with zinc tetroxychromate, eliminating the use of chromated compounds and combining high corrosion protection with a nontoxic, biodegradable, and environmentally friendly formulation.

The protection mechanism is based on the interaction of natural compounds with the metal surface, where they form a molecular network of chelates capable of stabilizing existing corrosion products and generating a continuous, adherent, and non-porous organic film. This passivating interfacial layer stabilizes the substrate and provides an excellent base for the adhesion of subsequent coatings.

Developed by BIOFLAV Ingenieria de Superficies, comparative studies of the primer conducted on SAE 1010 steel demonstrated superior performance compared to the benchmark commercial wash primer formulated with zinc tetroxychromate, achieving 92% corrosion protection efficiency under the evaluated conditions. While the chromated primer relies on active pigments that are progressively consumed during service, the organic film developed by BIO FLAV PRIMER maintained highly stable electrochemical behavior throughout the evaluation period.

As part of the current technological validation stage, prior to pre-pilot and pilot scale-up, the development is extending its evaluation to other carbon steels of industrial interest. For this purpose, an oil drilling rod made of SAE 4140 carbon steel, discarded after a failure mechanism in service and exhibiting significant surface deterioration, is being used. The use of a recovered industrial component previously subjected to severe operating conditions allows for the evaluation of the coating’s performance in a representative service scenario, providing evidence for the subsequent stages of technological scale-up and its future industrial and infrastructure implementation.

For more information:

BIOFLAV Ingenieria de Superficies

Image – Discarded SAE 4140 carbon steel oil drill rod following a failure in service, after several months of environmental exposure. The upper section, protected with BIO FLAV PRIMER, demonstrates the coating’s versatility: in previously corroded areas, it stabilizes corrosion products through chelation, while the untreated lower section, used as a reference, exhibits generalized oxidation.

Researchers uncover why cracks in materials break their symmetry while spreading

All materials, including those in our bodies and the structures around us, contain tiny imperfections like cracks, which can sometimes spread suddenly and dangerously—but also form fascinating patterns. Physicists have long struggled to explain why these cracks often branch unpredictably and slow down. However, two recent studies from the Weizmann Institute of Science have revealed that despite their chaotic appearance, crack propagation follows specific physical parameters that govern their behavior and explain the emergence of asymmetrical patterns.

Decades of controlled experiments in material failure have shown that even when a perfectly symmetrical crack is created under tensile forces, it spontaneously loses symmetry as it propagates, veering off course and moving more slowly than expected.

“These observations are the exact opposite of what we would expect based on theoretical calculations, which predict that even if we introduce a small obstacle in the path of a symmetrical crack under tension, the crack should return to a smooth, symmetrical trajectory,” says Prof. Eran Bouchbinder.

“Given the experimental evidence, we assumed that there must be missing links—overlooked physical properties that could account for the observed behavior.”

In one of the two studies led by Dr. Yuri Lubomirsky, then a doctoral student in Bouchbinder’s group in Weizmann’s Chemical and Biological Physics Department, the researchers used a computer model to simulate the propagation of cracks in three-dimensional materials.

“To understand crack propagation, we focused on the crack tip—the point where the material transitions from intact to fractured,” explains Lubomirsky. “While moderate conditions prevail throughout most of the material most of the time—meaning its behavior can often be understood by averaging its properties—the crack tip is governed by extreme conditions.

“Physical quantities such as force, temperature and velocity are so large there that they can be mathematically treated as approaching infinity, and the usual physical rules no longer apply. We postulated that the crack tip might reveal the hidden properties that explain asymmetrical crack propagation.”

The researchers’ arduous seven-year search for these missing physical properties was at times frustrating. “Ultimately, the breakthrough came from introducing significant disorder into the simulations—a factor previously overlooked in dynamic theories of material failure.

“We ran numerous simulations using advanced computing capabilities and observed that the crack initially moves straight until it reaches a point where it splits locally and then changes direction,” Bouchbinder says.

“The challenge was to extract from the vast amount of data the basic principle explaining why the crack branches out and deviates from a smooth, symmetrical path. One day, I asked Yuri to cross-reference two graphs, and that’s when it clicked: The intrinsic disorder of real-world materials, combined with the extreme conditions at the crack tip, turned out to be the missing link.”

The laws of physics explain the behavior of uniform materials fairly well, but most materials in the world are not truly uniform. Glass, for example, appears smooth and homogeneous, but a closer look at its particles and the connections between them reveals a structure lacking consistent order. This means that the internal forces acting within glass vary from one region to another.

Until now, engineers and scientists trying to understand fracture dynamics had relied on averaged material properties and thus failed to explain why cracks break symmetry. Bouchbinder and Lubomirsky realized that the answer lies in the extent of internal disorder—that is, how much the material’s strength varies from place to place.

The researchers applied varying fracture forces to their computer model and studied the relationship between crack propagation and material disorder. They observed that when fracture forces were weak, cracks propagated symmetrically without branching and were largely unaffected by disorder.

However, when fracture forces were moderate, cracks became sensitive to disorder: When the crack tip reached a weaker region, local instabilities developed, causing the crack to split locally instead of continuing in a straight line. These local branches competed with each other—one branch would stall while the other would continue as the main crack, often changing direction.

Retrospective examination of these regions revealed microcracks where the secondary branches had been arrested. In other words, in this regime the extent of branching depended directly on the degree of disorder.

Finally, when fracture forces exceeded a critical threshold, the crack no longer halted at points of instability but split into entirely separate branches that widened and penetrated deeper into the material. In this high-force regime, disorder once again played a minor role.

The deviation of cracks from their symmetry axis and the formation of branches come at an energetic cost: A larger amount of material is broken, and the crack’s velocity decreases relative to the speed it would have reached had it remained smooth and symmetrical.

Another phenomenon commonly seen in cracks—also linked to symmetry breaking—is the formation of steps composed of two interacting fracture surfaces. In a follow-up study the researchers investigated how this pattern forms.

They found that step formation depends not only on the degree of internal disorder but also on external tensile forces’ slight deviations from perfect symmetry. In addition to the tensile forces that open the crack, there are almost always perpendicular forces causing the crack’s faces to slide past each other in a rotational motion.

Incorporating both types of force and the internal disorder into their mathematical model, the scientists succeeded in predicting and explaining the emergence of the step pattern.

“These discoveries provide a physical and mathematical framework for understanding material failure through crack dynamics that we encounter in everyday life,” says Bouchbinder.

Lubomirsky adds, “Our findings could also help in designing materials that are more resilient to catastrophic cracking. We show that increasing disorder can slow crack propagation—an insight that could have significant implications for the design of structures and physical systems.

“Natural materials such as bones and teeth have evolved to resist failure, and it’s possible that their internal disorder is one of the key factors behind their resilience. This is where our findings also shed new light on the workings of nature.”

For more information: Nature Communications

Image: The crack driving force as a function of its propagation velocity in 2D and 3D, under different levels of disorder, and the emergence of a limiting crack velocity.

Enovis releases 2024 Corporate Social Responsibility Report highlighting commitment to sustainability and community engagement

Enovis Corporation, headquartered in Wilmington, Delaware, announced the publication of its 2024 Corporate Social Responsibility (CSR) report, underscoring the company’s ongoing dedication to ethical practices, environmental stewardship, and social responsibility. ​

The report details Enovis’ initiatives aimed at fostering a positive global impact. Key highlights include the implementation of energy-efficient technologies across manufacturing facilities, resulting in a measurable reduction in the company’s carbon footprint. Additionally, Enovis has expanded its community outreach programs, partnering with local organizations to support health and education initiatives.​

The CSR report also emphasizes Enovis’ commitment to diversity and inclusion within its workforce, showcasing programs designed to promote equitable opportunities and a supportive work environment for all employees. By aligning its business strategies with sustainable and socially responsible practices, Enovis aims to contribute meaningfully to the well-being of its stakeholders and the broader community.​

For a comprehensive overview of Enovis’ CSR initiatives and achievements, the full 2024 report is available on the company’s website.

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SECO/WARWICK finds the way to complete successful projects in Brazil

Seco/Warwick, Meadville, Pa., announced a significant milestone in its operations in Brazil. The company has successfully implemented a solution for Nitrion do Brasil, a leading commercial heat treater in South America, in their new production hall to manage the increasing order volume. This achievement underscores the strong synergy between SECO/WARWICK and its strategic partner in the region, Combustol.

SECO/WARWICK’s presence in Brazil has seen dynamic sales growth and promising market forecasts, driven by their popular Vector single-chamber vacuum furnaces. These furnaces are highly favored by commercial heat treaters in the region for their ability to enhance the hardening process and improve economic efficiency. The successful collaboration with Combustol has been instrumental, providing not only sales support but also service activities and the supply of spare parts, which has given SECO/WARWICK a competitive edge.

The Vector vacuum furnace ordered by Nitrion do Brasil is designed to address the challenge of hardening larger elements, thanks to its spacious working area. This feature enhances process economics through energy savings and increased efficiency of the graphite chamber, while also ensuring process cleanliness and speed. The furnace’s convection heating system improves heat transfer efficiency at lower temperatures, and its directional cooling system allows for effective cooling of parts with complex shapes.

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Solar Atmospheres acquires Certified Metal Craft Inc.

Solar Atmospheres, El Cajon, CA, , has announced the acquisition of Certified Metal Craft (CMC) based in El Cajon, California. This move marks Solar Atmospheres’ sixth nationwide location and enhances its presence on the West Coast.

Founded nearly 55 years ago, CMC has been a reputable and trusted service provider in the Southern California region, specializing in various heat treating processes including Vacuum, Aluminum, Atmospheric, Endothermic, Salt Bath, and Cryogenic processing. The company’s dedication to quality has earned it a Nadcap accreditation and a robust portfolio of customer and prime approvals in the Aerospace, Medical, and Commercial sectors.

This expansion not only solidifies Solar Atmospheres’ commitment to providing top-notch heat treating and brazing solutions but also underscores its industry-leading approach of integrity and honesty in all business dealings. The integration promises to bolster Solar’s operational capabilities and enhance its service offerings across the West Coast, ensuring that the company remains the “go-to” choice for clients in the sector.

Read further here.

Wisconsin Oven ships batch ovens to the manufacturing industry

Wisconsin Oven, East Troy, announced the shipment of two custom-designed Gas Fired Batch Ovens with roll-up doors. The ovens will be used to hold molded urethane wheels prior to a curing process.

The batch ovens have a maximum operating temperature of 350°F and work chamber dimensions of 9’ wide x 4’6” long x 10’6” high. The ovens are designed with electrically operated roll-up doors in the front of the oven constructed from high-temperature fabric. The door controls allow the door to open halfway or all the way by a command from a loading robot. In addition to the roll-up door on the front, a bi-parting, side-hinged, horizontal swing door is located on the rear of each oven.

These batch ovens feature a horizontal airflow arrangement, which is ideal for products arranged in multiple tiers where heated airflow cannot be directed vertically through the product. Both ovens utilize a Watlow F4T digital controller that includes a 4.3″ color touch screen, PID temperature control with adaptive tuning, and Ethernet communication capabilities for temperature control. A remote display for the flame relays is also mounted to each control panel to provide an annunciation of operation along with fault and diagnostic information.

 

https://www.wisoven.com/news/wisconsin-oven-ships-batch-ovens-manufacturing-industry