Research from King Abdullah University of Science and Technology, Saudi Arabia, shows that bandgap engineering can improve the performance of optoelectronic devices that aim to harness the energy of “hot” electrons.<\/p>\n
The simple idea of a bandgap defines a semiconductor\u2019s optical properties when energy from any absorbed light is transferred to the material\u2019s electrons. Most of the free electrons in a semiconductor have an energy near the top of the bandgap. But the absorption of photons with an energy much larger than the bandgap creates much higher energy electrons called \u201chot electrons.\u201d<\/p>\n
Understanding the process by which these hot electrons relax to an energy nearer the top of the bandgap is essential for understanding the operation of light-harvesting devices. For example, the efficiency of a solar cell is reduced if this huge excess energy is lost as heat. \u201cHowever, it was extremely difficult, if not impossible, to sufficiently utilize these hot electrons in real light-conversion applications due to their very short lifetimes,\u201d says material scientist Omar Mohammed.<\/p>\n
Mohammed and his colleagues used interface and bandgap engineering to delay hot carriers (electrons and holes) relaxation and to significantly increase their lifetimes.<\/p>\n
The team studied a semiconductor known as a lead halide perovskite. They designed and fabricated architectures made up of multiple quantum wells: a thin layer of semiconductor sandwiched between light-absorber layers of larger bandgap material. They compared the optical properties of structures in which the wells were all the same thickness and asymmetric structures in which the well widths varied. They used a technique called femtosecond transient absorption spectroscopy combined with theoretical calculations to determine the timescale of the hot electron relaxation.<\/p>\n
They found the cooling rate had a strong dependence on the quantum well thickness in the asymmetric sample and that the relaxation of the hot carriers in the asymmetric multiple quantum wells was 12.5-fold slower compared to that of the symmetric multiple quantum wells.<\/p>\n
\u201cThis new finding provides a unique strategy on how to significantly slow down the hot carriers cooling in semiconducting materials for their better utilization in solar cells applications,\u201d says postdoc Partha Maity.<\/p>\n
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