A new method could greatly reduce the time and expense needed for certain important safety checks in nuclear power reactors. The approach could save money and increase total power output in the short run, and it might increase plants’ safe operating lifetimes in the long run.

One of the most effective ways to control greenhouse gas emissions, many analysts argue, is to prolong the lifetimes of existing nuclear power plants. But extending these plants beyond their originally permitted operating lifetimes requires monitoring the condition of many of their critical components to ensure that damage from heat and radiation has not led, and will not lead, to unsafe cracking or embrittlement.

Today, testing of a reactor’s stainless-steel components — which make up much of the plumbing systems that prevent heat buildup, as well as many other parts — requires removing test pieces, known as coupons, of the same kind of steel that are left adjacent to the actual components, so they experience the same conditions. Or, it requires the removal of a tiny piece of the actual operating component. Both approaches are done during costly shutdowns of the reactor, prolonging these scheduled outages and costing millions of dollars per day.

Now, researchers at MIT and elsewhere have come up with a new, inexpensive, hands-off test that can produce similar information about the condition of these reactor components, with far less time required during a shutdown. The findings are reported today in the journal Acta Materiala in a paper by MIT professor of nuclear science and engineering Michael Short, Saleem Al Dajani a doctoral student at the King Abdullah University of Science and Technology (KAUST) in Saudi Arabia, and 13 others at MIT and other institutions.

The test involves aiming laser beams at the stainless-steel material, which generates surface acoustic waves (SAWs) on the surface. Another set of laser beams is then used to detect and measure the frequencies of these SAWs. Tests on material aged identically to nuclear power plants showed that the waves produced a distinctive double-peaked spectral signature when the material was degraded.

Short and Al Dajani embarked on the process in 2018, looking for a more rapid way to detect a specific kind of degradation, called spinodal decomposition, that can take place in austenitic stainless steel. This process can lead to embrittlement, cracking, and potential failure in the event of an emergency.

While spinodal decomposition is not the only type of degradation that can occur in reactor components, it is a primary concern for the lifetime and sustainability of nuclear reactors, Short says.

They decided to try a technique Short and his students and collaborators had expanded upon, called transient grating spectroscopy, or TGS, on samples of reactor materials known to have experienced spinodal decomposition as a result of their reactor-like thermal aging history. The method uses laser beams to stimulate, and then measure, SAWs on a material. The idea was that the decomposition should slow down the rate of heat flow through the material, that slowdown would be detectable by the TGS method.

However, it turns out there was no such slowdown. “We went in with a hypothesis about what we would see, and we were wrong,” Short says.

Instead, what showed up in the data was that, while a material would usually produce a single frequency peak for the material’s SAWs, in the degraded samples there was a splitting into two peaks.

Cast austenitic stainless steels like those used in reactor components are what’s known as duplex steels, actually a mixture of two different crystal structures in the same material by design. But while one of the two types is quite impervious to spinodal decomposition, the other is quite vulnerable to it. When the material starts to degrade, the difference shows up in the different frequency responses of the material, which is what the team found in their data.

The tests they did used large lab-based lasers and optical systems, so the next step, which the researchers are hard at work on, is miniaturizing the whole system into something that can be an easily portable test kit to use to check reactor components on-site, reducing the length of shutdowns.

Short hopes that this could help to enable the extension of power plant operating licenses for some additional decades without compromising safety, by enabling frequent, simple and inexpensive testing of the key components. Existing, large-scale plants “generate just shy of a billion dollars in carbon-free electricity per plant each year,” he says, whereas bringing a new plant online can take more than a decade. “To bridge that gap, keeping our current nukes online is the single biggest thing we can do to fight climate change.”

For more information: MIT

Physicists at Leipzig University have once again gained a deeper understanding of the mechanism behind superconductors. This brings the research group led by Professor Jürgen Haase one step closer to their goal of developing the foundations for a theory for superconductors that would allow current to flow without resistance and without energy loss. The researchers found that in superconducting copper-oxygen bonds, called cuprates, there must be a very specific charge distribution between the copper and the oxygen, even under pressure.

This confirmed their own findings from 2016, when Haase and his team developed an experimental method based on magnetic resonance that can measure changes that are relevant to superconductivity in the structure of materials. They were the first team in the world to identify a measurable material parameter that predicts the maximum possible transition temperature, a condition required to achieve superconductivity at room temperature. Now they have discovered that cuprates, which under pressure enhance superconductivity, follow the charge distribution predicted in 2016. The researchers have published their new findings in the journal PNAS.

“The fact that the transition temperature of cuprates can be enhanced under pressure has puzzled researchers for 30 years. But until now we didn’t know which mechanism was responsible for this,” Haase said.

He and his colleagues at the Felix Bloch Institute for Solid State Physics have now come a great deal closer to understanding the actual mechanism in these materials.

“At Leipzig University we have established the basic conditions needed to research cuprates using nuclear resonance, and Michael Jurkutat was the first doctoral researcher to join us. Together, we established the Leipzig Relation, which says that you have to take electrons away from the oxygen in these materials and give them to the copper in order to increase the transition temperature. You can do this with chemistry, but also with pressure. But hardly anyone would have thought that we could measure all of this with nuclear resonance,” Haase said.

Their current research findings could be exactly what is needed to produce a superconductor at room temperature, which has been the dream of many physicists for decades and is now expected to take only a few more years, according to Haase. To date, this has only been possible at very low temperatures around minus 150 degrees Celsius and below, which are not easy to find anywhere on Earth. About a year ago, a Canadian research group verified the findings of Professor Haase’s team from 2016 using newly developed, computer-aided calculations and thus substantiated the findings theoretically.

Superconductivity is already used today in a variety of ways, but it would be much easier and less expensive if superconductors operated at room temperature.

For more information: Leipzig University