Carbon fiber project partnership

Harper International, Cheektowaga, N.Y. and Oak Ridge National Laboratory (ORNL), Tenn., were awarded funding for a project through the DOE’s Advanced Manufacturing Office’s HPC4Mfg Program.

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Growing gold for biomedical procedures

Grown like a snowflake and sharpened with a sewing machine, a novel device by Kansas State University researchers may benefit biomedical professionals and the patients they serve during electrode and organ transplant procedures.

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Sensing skin spots cracks in structures

Researchers have developed a multi-layered “sensing skin” to detect corrosive or otherwise harmful substances in structures. The skin can also detect cracks and other structural flaws that are invisible to the naked eye.

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Finding alloys to form bulk metallic glass

Researchers from the Harvard John A. Paulson School of Engineering and Applied Sciences (SEAS), Cambridge, Mass., in collaboration with colleagues from Duke and Yale universities, recently developed a method to predict which alloys might form a bulk metallic glass.

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New wetsuit inspired by beavers

Inspired by beavers, engineers at MIT fabricated fur-like, rubbery pelts and used them to identify a mechanism by which air is trapped between individual hairs when the pelts are plunged into liquid.

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NSF center focuses on real-time functional imaging

The National Science Foundation (NSF), Arlington, Va., announced $24 million in funding to support a new science and technology center at the University of Colorado Boulder, expanding the university’s role as a national leader in imaging, materials, nano, bio, and energy sciences.

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Self-healing crystal mimics skin

Scientists developed a smart crystal that can heal itself after breaking without any chemical or biological intervention. The crystal relies on its own molecular structure and physical contact to heal—similar to cuts on skin.

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Video: Smart threads could save lives

Engineers are joining forces with designers, scientists and doctors at Drexel University, Philadelphia, to produce new biomedical textiles, which are not only fashionably functional, but could also be life savers.

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Fluorescence boosts cool colored pigment performance

Elementary school science teaches us that in the sun, dark colors get hot while white stays cool. Now new research from Lawrence Berkeley National Laboratory (Berkeley Lab), Calif., has found an exception: Certain dark pigments can stay just as cool as white by using fluorescence, the re-emission of absorbed light.

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New material holds promise for low power electronics

Scientists have successfully paired ferroelectric and ferrimagnetic materials so that their alignment can be controlled with a small electric field at near room temperatures, an achievement that could open doors to ultralow-power microprocessors, storage devices, and next-generation electronics.

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Graphene goes into silicon at room temperature

Materials researchers at North Carolina State University, Raleigh, developed a technique that allows the integration of graphene, graphene oxide (GO), and reduced graphene oxide (rGO) onto silicon substrates at room temperature by using nanosecond pulsed laser annealing.

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Enhanced 3D look inside batteries

A team of chemists has developed a method to yield highly detailed, 3D images of the insides of batteries. The technique, based on magnetic resonance imaging (MRI), offers an enhanced approach to monitor the condition of these power sources in real time.

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Understanding semiconductor stability aids next generation materials development

While metal oxide semiconductors have been widely considered to exhibit outstanding durability, performance degradation in these solar energy harvesting components happens frequently. Understanding the degradation is essential for developing stable, efficient photosystems. To address the failure, a team at the Joint Center for Artificial Photosynthesis, Calif., uncovered the mysteries of photochemical instability in a widely used semiconductor. Their results reveal previously unpredicted pathways to degradation and provide insights.

Production of fuels from sunlight, carbon dioxide, and water relies on semiconductors that can resist corrosion in harsh operating conditions. Predicting and understanding the origin and pathways associated with the degradation of semiconductors is crucial to designing a next generation of robust and efficient materials.

Artificial photosynthesis, which is the process of conversion of sunlight, carbon dioxide, and water into fuels, relies on chemically stable materials that can efficiently harvest solar energy under harsh operating conditions. Artificial systems must be constructed from robust components that can sustain years of operation without the need for energy-intensive and costly repairs. Currently, the lack of durable and efficient semiconductors and the complexity of fabricating stable assemblies are major roadblocks to the realization of viable artificial photosystems. In recent years, significant effort has been directed at developing novel protection schemes that can prolong the lifetimes of otherwise unstable materials.

While these approaches have met with success, understanding—and then predicting—corrosion processes of semiconductors will greatly aid the discovery and development of materials that are inherently stable. To promote such understanding, scientists from the Joint Center for Artificial Photosynthesis used experimental and theoretical tools to assess the mechanisms underlying the degradation of bismuth vanadate in the working conditions present in a solar fuels device. Bismuth vanadate is currently one of the best materials available for fabricating semiconductor photoanodes to split water into hydrogen fuel and oxygen.

The study reveals that kinetic factors play a critical role in defining corrosion pathways. Indeed, accumulation of light-generated charge at the surface of the bismuth vanadate destabilizes the material. These and other insights will guide approaches to stabilization and aid the search for durable, visible-light-absorbing materials for the next generation of solar-to-fuel conversion systems.

This study is based on work performed at the Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, supported through the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences under award number DE-SC0004993. Imaging work at the Molecular Foundry was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under contract number DE-AC02-05CH11231. The in situ electrochemical atomic force microscopy part of this work was supported in part by the Laboratory Directed Research and Development Program of Lawrence Berkeley National Laboratory under U.S. Department of Energy contract number DE-AC02-05CH11231. V.K. and F.M.T. acknowledge support from the Bavaria California Technology Center programme, project number 2015-1.

Image caption — A solar simulator illuminates a photoelectrochemical cell that contains a bismuth vanadate thin-film electrode to harvest light. Courtesy of Joint Center for Artificial Photosynthesis and Paul Mueller (Lawrence Berkeley National Laboratory).